Synthesis of trans-mono(silyl)palladium(II) bromide complexes

Ansell, Melvyn B, Kostakis, George E, Navarro, Oscar and Spencer, John (2021) Synthesis of trans-mono(silyl)palladium(II) bromide complexes. Molecules, 26 (9). a2460 1-6. ISSN 1420-3049

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Abstract

The stoichiometric reaction of cis-[Pd(ITMe)2(SiR3)2], where (SiR3 = SiMe3 and SiMe2Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)2(SiR3)(Br)]. The structure of trans-[Pd(ITMe)2(SiMe2Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
SWORD Depositor: Mx Elements Account
Depositing User: Mx Elements Account
Date Deposited: 26 Apr 2021 06:54
Last Modified: 11 Jun 2021 16:30
URI: http://sro.sussex.ac.uk/id/eprint/98642

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