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(N-heterocyclic carbene)-Pd-catalyzed anaerobic oxidation of secondary alcohols and domino oxidation-arylation reactions
journal contribution
posted on 2023-06-08, 14:58 authored by Brant Landers, Christophe Berini, Chao Wang, Oscar Navarro FernandezThe use of commercially available (SIPr)Pd(cinnamyl)Cl (SIPr = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene) as a precatalyst for the anaerobic oxidation of secondary alcohols is described. The use of this complex allows for a drastic reduction in the reaction times and catalyst loading when compared to the unsaturated counterpart. This catalytic system is compatible with the use of microwave dielectric heating, decreasing even further catalyst loading and reaction times. Domino Pd-catalyzed oxidation-arylation reactions of secondary alcohols are also presented.
History
Publication status
- Published
Journal
Journal of Organic ChemistryISSN
0022-3263Publisher
American Chemical SocietyExternal DOI
Issue
5Volume
76Page range
1390-1397Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2013-05-20Usage metrics
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