The first example of simple oxidative addition of an aryl chloride to a discrete palladium (n-heterocyclic carbene) amination precatalyst

Caddick, Stephen, Cloke, F Geoffrey N, Hitchcock, Peter B, Leonard, John, Lewis, Alexandra K de K, McKerrecher, Darren and Titcomb, Lisa R (2002) The first example of simple oxidative addition of an aryl chloride to a discrete palladium (n-heterocyclic carbene) amination precatalyst. Organometallics, 21 (21). pp. 4318-4319. ISSN 02767333

Full text not available from this repository.

Abstract

The oxidative addition of an aryl chloride to a discrete palladium n-heteocyclic carbene amination precatalyst, was discussed. It was found that the oxidative addition of 4-chlorotoluene to Pd(0) resulted in the formation of not a four-coordinate complex but rather the arylated imidazolium salt. The identity of imidazolium salt was confirmed by x-ray crystallography.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:54
Last Modified: 07 Jan 2020 16:22
URI: http://sro.sussex.ac.uk/id/eprint/28651
📧 Request an update