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The sulfinyl moiety in Lewis base-promoted allylations

journal contribution
posted on 2023-06-08, 08:01 authored by J Robin Fulton, Lamin M Kamara, Simon C Morton, Gareth J Rowlands
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.

History

Publication status

  • Published

Journal

Tetrahedron

ISSN

0040-4020

Publisher

Elsevier

Issue

45

Volume

65

Page range

9134-9141

Pages

8.0

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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