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An Organozinc Hydride Cluster: an Encapsulated Tetrahydrozincate?

journal contribution
posted on 2023-06-08, 07:19 authored by Martyn P Coles, Salima M El-Hamruni, J David Smith, Peter B Hitchcock
Reaction of the alkylzinc bromide Zn(C{SiMe3}2{SiMe2hpp})Br (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine) with an excess of sodium hydride gives good yields of an unusual zinc hydride cluster, in which five zinc atoms are linked by (-H) bridges

History

Publication status

  • Published

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Publisher

Wiley

External DOI

Issue

52

Volume

47

Page range

10147-10150

Pages

4.0

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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