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Structural diversity in organolithium -sodium and -potassium cycanocuprates
journal contribution
posted on 2023-06-08, 07:07 authored by Colin Eaborn, Michael S Hill, Peter B Hitchcock, J David SmithAn unprecedented series of “lower order” alkali metal (Li, Na, K) cyanocuprates containing the bulky (Me2PhSi)3C ligand has been synthesized. Both monomeric and dimeric forms of the lithium derivative have been characterized; the tetrameric potassium compound provides a striking example of molecular self-assembly driven by K-p-aryl interactions.
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Publication status
- Published
Journal
OrganometallicsISSN
0276-7333Publisher
American Chemical SocietyExternal DOI
Volume
19Page range
5780-5783ISBN
0276-7333Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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