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Isolation and characterisation ofCs-symmetryC60Me5O2OH, the first methylatedfullerenol; a bis-epoxide with two oxygens in a pentagonal ring

journal contribution
posted on 2023-06-08, 06:50 authored by Hamad Al-Matar, Peter B Hitchcock, Anthony G Avent, Roger Taylor
From the reaction between [60]fullerene and MeLi, we have isolated C60Me5O2OH, which has been characterised by both 1H and 13C NMR spectroscopy and by single-crystal X-ray analysis; uniquely, both epoxide groups bridge 5 : 6-bonds in the same pentagon.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Volume

12

Page range

1071 - 1072

ISBN

1359-7345

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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