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Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems: Crystal and molecular structure of P2C2Bu(t)2NPh

journal contribution
posted on 2023-06-08, 05:02 authored by Geoff Cloke, Peter B Hitchcock, John F Nixon, D James Wilson, Frank Tabellion, Uwe Fischbeck, Fritz Preuss, Manfred Regitz
Two different synthetic routes to the new aromatic 1,2,4-aza-diphosphole ring system P2C2Bu(t)2NR (R = Pr(i), Pr, Ph, MeC6H4, Bu(t)CH2 and cyclohexyl) are presented and the planar structure of P2C2Bu(t)2NPh, established by a single crystal X-ray diffraction study, is in good agreement with theoretical calculations at the B3LYP/6-311G* level on the parent P2C2H2NH ring.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

13597345

Issue

23

Volume

-

Page range

2363-2364

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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