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Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds; a Spectroscopic and Crystallographic Study

journal contribution
posted on 2023-06-07, 23:37 authored by Natalie E Mansfield, Martyn P Coles, Anthony G Avent, Peter B Hitchcock
Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N'-bound bimetallic aluminum species and monometallic platinum complexes in which the ligand chelates to the metal through the two phosphorus donor atoms.

History

Publication status

  • Published

Journal

Organometallics

ISSN

0276-7333

Issue

10

Volume

25

Page range

2470 - 2474

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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