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First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(Pr(i)NH)2CH2Bu(t)}2]

journal contribution
posted on 2023-06-07, 21:40 authored by Geoff Cloke, Peter B Hitchcock, John F Nixon, D James Wilson
Treatment of a dichloromethane solution of Bu(t)CP, containing a catalytic amount of TiCl4, with an excess of the primary amines RNH2 (R = Pr(i), Bu(t)) quantitatively affords the corresponding bis-dialkylaminophosphine P(Bu(t)NH)2-CH2Bu(t). P(Pr(i)NH)2CH2Bu(t) is structurally characterised by a single crystal X-ray diffraction study of its bis-trans-PdCl2 complex.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

13597345

Issue

23

Volume

-

Page range

2387-2388

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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