molecules-26-02460.pdf (607.4 kB)
Synthesis of trans-mono(silyl)palladium(II) bromide complexes
journal contribution
posted on 2023-06-09, 23:43 authored by Melvyn B Ansell, George KostakisGeorge Kostakis, Oscar Navarro, John SpencerJohn SpencerThe stoichiometric reaction of cis-[Pd(ITMe)2(SiR3)2], where (SiR3 = SiMe3 and SiMe2Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)2(SiR3)(Br)]. The structure of trans-[Pd(ITMe)2(SiMe2Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration.
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MoleculesISSN
1420-3049Publisher
MDPIExternal DOI
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9Volume
26Page range
1-6Article number
a2460Department affiliated with
- Chemistry Publications
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Legacy Posted Date
2021-04-26First Open Access (FOA) Date
2021-04-26First Compliant Deposit (FCD) Date
2021-04-26Usage metrics
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