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Synthesis of trans-mono(silyl)palladium(II) bromide complexes

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posted on 2023-06-09, 23:43 authored by Melvyn B Ansell, George KostakisGeorge Kostakis, Oscar Navarro, John SpencerJohn Spencer
The stoichiometric reaction of cis-[Pd(ITMe)2(SiR3)2], where (SiR3 = SiMe3 and SiMe2Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)2(SiR3)(Br)]. The structure of trans-[Pd(ITMe)2(SiMe2Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration.

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  • Published

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  • Published version

Journal

Molecules

ISSN

1420-3049

Publisher

MDPI

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Issue

9

Volume

26

Page range

1-6

Article number

a2460

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  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2021-04-26

First Open Access (FOA) Date

2021-04-26

First Compliant Deposit (FCD) Date

2021-04-26

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