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Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates
Version 2 2023-06-12, 09:44
Version 1 2023-06-09, 23:03
journal contribution
posted on 2023-06-12, 09:44 authored by Stephan Hagspiel, Merle Arrowsmith, Felipe Fantuzzi, Alfredo VargasAlfredo Vargas, Anna Rempel, Alexander Hermann, Tobias Brückner, Holger BraunschweigReduction of (CAAC)BBr2(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.
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Publication status
- Published
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- Published version
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
WileyExternal DOI
Issue
12Volume
60Page range
6446-6450Event location
GermanyDepartment affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2021-02-12First Open Access (FOA) Date
2021-02-12First Compliant Deposit (FCD) Date
2021-02-12Usage metrics
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