Hagspiel, Stephan, Arrowsmith, Merle, Fantuzzi, Felipe, Vargas, Alfredo, Rempel, Anna, Hermann, Alexander, Brückner, Tobias and Braunschweig, Holger (2021) Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates. Angewandte Chemie International Edition, 60 (12). pp. 6446-6450. ISSN 1433-7851

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Abstract

Reduction of (CAAC)BBr2(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z‐isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)‐stabilized, boron‐doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.

Item Type:	Article
Keywords:	DFT, aromaticity, borylenes, fused thiazaboroles, reduction
Schools and Departments:	School of Life Sciences > Chemistry
SWORD Depositor:	Mx Elements Account
Depositing User:	Mx Elements Account
Date Deposited:	12 Feb 2021 08:42
Last Modified:	04 Jun 2021 13:34
URI:	http://sro.sussex.ac.uk/id/eprint/97109

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