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Highly colored boron-doped thiazolothiazoles from the reductive dimerization of boron isothiocyanates

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Version 2 2023-06-12, 09:44
Version 1 2023-06-09, 23:03
journal contribution
posted on 2023-06-12, 09:44 authored by Stephan Hagspiel, Merle Arrowsmith, Felipe Fantuzzi, Alfredo VargasAlfredo Vargas, Anna Rempel, Alexander Hermann, Tobias Brückner, Holger Braunschweig
Reduction of (CAAC)BBr2(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.

History

Publication status

  • Published

File Version

  • Published version

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Publisher

Wiley

Issue

12

Volume

60

Page range

6446-6450

Event location

Germany

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2021-02-12

First Open Access (FOA) Date

2021-02-12

First Compliant Deposit (FCD) Date

2021-02-12

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