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Hematite coated, conductive Y doped ZnO nanorods for high efficiency solar water splitting
journal contribution
posted on 2023-06-09, 20:45 authored by Daniel Holt, Joshua McGuckin, Qiao ChenQiao ChenFor the first time, hematite (a-Fe2O3) crystals were electrochemically deposited over vertically aligned conductive zinc oxide nanorods (NR) to form a specially designed 3D heterostructure with a unique triple layer structure. The structure formed with a thin layer of ZnFe2O4 sandwiched between the hematite and the ZnO, which forms a barrier to reduce the back migration of holes. Hence, the charge separation is significantly improved. The small unequal band gaps of a-Fe2O3 and ZnFe2O4 help to enhance and broaden visible light absorption. The electron transportation was further improved by yttrium doping in the ZnO (YZnO) NRs, resulting in increased conductivity. This allowed the vertically aligned NRs to perform as electron highways, which also behave as effective optical waveguides for improved light trapping and absorption, since ZnO absorbs little visible light. All these benefits made the unique structures suitable for high performance photoelectrochemical (PEC) water splitting. Optimisation of a-Fe2O3 thickness led to a photocurrent density improvement from 0.66 to 0.95 mA cm-2 at 1.23 VRHE. This was further improved to 1.59 mA cm-2 by annealing at 550°C for 3 hours, representing a record-breaking photocurrent for a-Fe2O3/ZnO systems. Finally IPCE confirmed the successful generation and transfer of photoelectrons under visible light excitation in the specifically designed heterostructure photoanode, with 5% efficiency for blue light, and 15% for violet light.
History
Publication status
- Published
File Version
- Accepted version
Journal
NanotechnologyISSN
0957-4484Publisher
IOP PublishingExternal DOI
Issue
26Volume
31Page range
1-11Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2020-03-03First Open Access (FOA) Date
2020-03-03First Compliant Deposit (FCD) Date
2020-03-02Usage metrics
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