Schmidt, Uwe, Werner, Luis, Arrowsmith, Merle, Deissenberger, Andrea, Hermann, Alexander, Hofmann, Alexander, Ullrich, Stefan, Mattock, James D, Vargas, Alfredo and Braunschweig, Holger (2020) Trans‐selective insertional dihydroboration of a cis‐diborene: synthesis of linear sp3‐sp2‐sp3‐triboranes and subsequent cationization. Angewandte Chemie International Edition, 59 (1). pp. 325-329. ISSN 1433-7851

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Abstract

The reaction of aryl‐ and amino(dihydro)boranes with dibora[2]ferrocenophane 1 leads to the formation 1,3‐trans‐dihydrotriboranes by formal hydrogenation and insertion of a borylene unit into the B=B bond. The aryltriborane derivatives undergo reversible photoisomerization to the cis‐1,2-μ‐H‐3hydrotriboranes, while hydride abstraction affords cationic triboranes, which represent the first doubly base‐stabilized B3H4+ analogues.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Subjects:	Q Science > QD Chemistry
Depositing User:	Alfredo Vargas
Date Deposited:	08 Nov 2019 10:32
Last Modified:	17 Jun 2020 11:00
URI:	http://sro.sussex.ac.uk/id/eprint/87896

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