Sonochemical edge functionalisation of molybdenum disulfide

Amorim Graf, Aline, Large, Matthew, Ogilvie, Sean Paul, Rong, Yuanyang, Lynch, Peter, Fratta, Giuseppe, Ray, Santanu, Shmeliov, Aleksey, Nicolosi, Valeria, Arenal, Raul, King, Alice A K and Dalton, Alan B (2019) Sonochemical edge functionalisation of molybdenum disulfide. Nanoscale. ISSN 2040-3364

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Liquid-phase exfoliation (LPE) has been shown to be capable of producing large quantities of high-quality dispersions suitable for processing into subsequent applications. LPE typically requires surfactants for aqueous dispersions or organic solvents with high boiling point. However, they have major drawbacks such as toxicity, aggregation during solvent evaporation or the presence of residues. Here, dispersions of molybdenum disulfide in acetone are prepared and show much higher concentration and stability than predicted by Hansen parameter analysis. Aiming to understand those enhanced properties, the nanosheets were characterised using UV-visible spectroscopy, zeta potential measurements, atomic force microscopy, Raman spectroscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and scanning transmission microscopy combined with spatially-resolved electron energy loss spectroscopy. Also, the performance of the MoS2 nanosheets exfoliated in acetone was compared to those exfoliated in isopropanol as a catalyst for the hydrogen evolution reaction. The conclusion from the chemical characterisation was that MoS2 nanosheets exfoliated in acetone have an oxygen edge-functionalisation, in the form of molybdenum oxides, changing its interaction with solvents and explaining the observed high-quality and stability of the resulting dispersion in a low boiling point solvent. Exfoliation in acetone could potentially be applied as a pretreatment to modify the solubility of MoS2 by edge-functionalisation.

Item Type: Article
Schools and Departments: School of Mathematical and Physical Sciences > Physics and Astronomy
Research Centres and Groups: Materials Physics Group
Subjects: Q Science > QC Physics
Depositing User: Aline Amorim Graf
Date Deposited: 06 Aug 2019 09:30
Last Modified: 05 Aug 2020 01:00

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