Phosphine stabilized diiododiborenes: isolable diborenes with six labile bonds

Muessig, Jonas H, Thaler, Melanie, Dewhurst, Rian D, Paprocki, Valerie, Seufert, Jens, Mattock, James D, Vargas, Alfredo and Braunschweig, Holger (2019) Phosphine stabilized diiododiborenes: isolable diborenes with six labile bonds. Angewandte Chemie International Edition. ISSN 1433-7851

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Abstract

The lability of B=B, B‐P and B‐halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Alfredo Vargas
Date Deposited: 25 Feb 2019 11:45
Last Modified: 25 Feb 2019 11:45
URI: http://sro.sussex.ac.uk/id/eprint/82034

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