University of Sussex
Browse
Manuscript Diiododiborenes_final.pdf (773.27 kB)

Phosphine stabilized diiododiborenes: isolable diborenes with six labile bonds

Download (773.27 kB)
journal contribution
posted on 2023-06-09, 16:55 authored by Jonas H Muessig, Melanie Thaler, Rian D Dewhurst, Valerie Paprocki, Jens Seufert, James D Mattock, Alfredo VargasAlfredo Vargas, Holger Braunschweig
The lability of B=B, B-P and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.

History

Publication status

  • Published

File Version

  • Accepted version

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Publisher

Wiley

Issue

13

Volume

131

Page range

4451-4456

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2019-02-25

First Open Access (FOA) Date

2020-02-04

First Compliant Deposit (FCD) Date

2019-02-25

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC