Manuscript_dihydroboryl.pdf (1.13 MB)
Facile synthesis of a stable dihydroboryl {BH2}– anion
journal contribution
posted on 2023-06-09, 15:13 authored by Merle Arrowsmith, James D Mattock, Stephan Hagspiel, Ivo Krummenacher, Alfredo VargasAlfredo Vargas, Holger BraunschweigWhile the one-electron reduction of (CAACMe)BH2Br (CAACMe = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) yields a hydride-shift isomer of the corresponding tetrahydrodiborane, a further reversible reduction leads to the first stable parent boryl anion, [(CAACMe)BH2]–, which acts as a powerful boron nucleophile.
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Publication status
- Published
File Version
- Accepted version
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
WileyExternal DOI
Issue
46Volume
57Page range
15272-15275Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2018-09-25First Open Access (FOA) Date
2019-09-20First Compliant Deposit (FCD) Date
2018-09-25Usage metrics
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