3d-4f_perspective_final_090718_revised_colourless.pdf (2.27 MB)
Transformative 3d-4f coordination clusters carriers
journal contribution
posted on 2023-06-09, 14:07 authored by Kieran Griffiths, George KostakisGeorge KostakisThe aim of this perspective is to summarise the use of the reported 3d-4f Coordination Clusters (CCs) in catalytic reactions and to demonstrate the potential of this emerging field. The pioneering work of Shibasaki, Matsunaga and others, demonstrated the use of 3d-4f in-situ systems to catalyse asymmetric organic transformations. Our recent studies show that well characterised 3d-4f CCs catalyse numerous organic transformations and useful mechanistic aspects of their catalysis can be obtained. Furthermore, we have shown that by manipulation of the metal ion coordination environment; the nature of the 3d and lanthanide ions and the organic periphery of the ligand can all improve the efficacy of a 3d-4f CC catalyst. All in-situ formed and well characterized 3d-4f CCs involved in catalysis are discussed.
Funding
Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties; G1632; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/M023834/1
History
Publication status
- Published
File Version
- Accepted version
Journal
Dalton TransactionsISSN
1477-9226Publisher
Royal Society of ChemistryExternal DOI
Issue
35Volume
47Page range
12011-12034Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2018-07-10First Open Access (FOA) Date
2019-07-10First Compliant Deposit (FCD) Date
2018-07-10Usage metrics
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