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Transformative 3d-4f coordination clusters carriers

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journal contribution
posted on 2023-06-09, 14:07 authored by Kieran Griffiths, George KostakisGeorge Kostakis
The aim of this perspective is to summarise the use of the reported 3d-4f Coordination Clusters (CCs) in catalytic reactions and to demonstrate the potential of this emerging field. The pioneering work of Shibasaki, Matsunaga and others, demonstrated the use of 3d-4f in-situ systems to catalyse asymmetric organic transformations. Our recent studies show that well characterised 3d-4f CCs catalyse numerous organic transformations and useful mechanistic aspects of their catalysis can be obtained. Furthermore, we have shown that by manipulation of the metal ion coordination environment; the nature of the 3d and lanthanide ions and the organic periphery of the ligand can all improve the efficacy of a 3d-4f CC catalyst. All in-situ formed and well characterized 3d-4f CCs involved in catalysis are discussed.

Funding

Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties; G1632; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/M023834/1

History

Publication status

  • Published

File Version

  • Accepted version

Journal

Dalton Transactions

ISSN

1477-9226

Publisher

Royal Society of Chemistry

Issue

35

Volume

47

Page range

12011-12034

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2018-07-10

First Open Access (FOA) Date

2019-07-10

First Compliant Deposit (FCD) Date

2018-07-10

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