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Single-molecule magnet properties of a monometallic dysprosium pentalene complex
journal contribution
posted on 2023-06-09, 13:34 authored by Alexander Kilpatrick, Fu-Sheng Guo, Benjamin M Day, Akseli Mansikkamäki, Richard LayfieldRichard Layfield, Geoff ClokeThe pentalene-ligated dysprosium complex [(?8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2–) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm–1. Whilst the [Cp*]– ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2– ligand.
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- Published
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- Accepted version
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
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51Volume
54Page range
7085-7088Department affiliated with
- Chemistry Publications
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- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2018-05-30First Open Access (FOA) Date
2019-05-30First Compliant Deposit (FCD) Date
2018-05-30Usage metrics
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