Single-molecule magnet properties of a monometallic dysprosium pentalene complex

Kilpatrick, Alexander, Guo, Fu-Sheng, Day, Benjamin M, Mansikkamäki, Akseli, Layfield, Richard A and Cloke, F Geoffry (2018) Single-molecule magnet properties of a monometallic dysprosium pentalene complex. Chemical Communications, 54 (51). pp. 7085-7088. ISSN 1359-7345

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Abstract

The pentalene-ligated dysprosium complex [(8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2–) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm–1. Whilst the [Cp*]– ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2– ligand.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
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Depositing User: Richard Layfield
Date Deposited: 30 May 2018 14:09
Last Modified: 12 Jul 2019 16:01
URI: http://sro.sussex.ac.uk/id/eprint/76233

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