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Kilpatrick, Alexander, Guo, Fu-Sheng, Day, Benjamin M, Mansikkamäki, Akseli, Layfield, Richard A and Cloke, F Geoffry (2018) Single-molecule magnet properties of a monometallic dysprosium pentalene complex. Chemical Communications, 54 (51). pp. 7085-7088. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/C8CC03516D
Abstract
The pentalene-ligated dysprosium complex [(8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2–) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm–1. Whilst the [Cp*]– ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2– ligand.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Related URLs: | |
Depositing User: | Richard Layfield |
Date Deposited: | 30 May 2018 14:09 |
Last Modified: | 12 Jul 2019 16:01 |
URI: | http://sro.sussex.ac.uk/id/eprint/76233 |
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