Iron- and cobalt-catalyzed synthesis of carbene phosphinidenes

Pal, Kuntal, Hemming, Oliver B, Day, Benjamin M, Pugh, Thomas, Evans, David J and Layfield, Richard (2015) Iron- and cobalt-catalyzed synthesis of carbene phosphinidenes. Angewandte Chemie International Edition, 55 (5). pp. 1690-1693. ISSN 1433-7851

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Abstract

In the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)·PAr. The formation of (IMe4)·PMes (Mes=mesityl) is also catalysed by the phosphinidene-bridged complex [(IMe4)2Fe-(m-PMes)]2, which provides evidence for metal-catalysed phosphinidene
transfer.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Anna Izykowska
Date Deposited: 07 Sep 2018 08:46
Last Modified: 02 Jul 2019 14:35
URI: http://sro.sussex.ac.uk/id/eprint/75397

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