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Pal, Kuntal, Hemming, Oliver B, Day, Benjamin M, Pugh, Thomas, Evans, David J and Layfield, Richard (2015) Iron- and cobalt-catalyzed synthesis of carbene phosphinidenes. Angewandte Chemie International Edition, 55 (5). pp. 1690-1693. ISSN 1433-7851
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Official URL: http://dx.doi.org/10.1002/anie.201508303
Abstract
In the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)·PAr. The formation of (IMe4)·PMes (Mes=mesityl) is also catalysed by the phosphinidene-bridged complex [(IMe4)2Fe-(m-PMes)]2, which provides evidence for metal-catalysed phosphinidene
transfer.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry |
Depositing User: | Anna Izykowska |
Date Deposited: | 07 Sep 2018 08:46 |
Last Modified: | 02 Jul 2019 14:35 |
URI: | http://sro.sussex.ac.uk/id/eprint/75397 |
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