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Leech, Matthew C and Crossley, Ian R (2018) Through-conjugation of two phosphaalkyne (‘CP’) moieties mediated by a bimetallic scaffold†. Dalton Transactions, 47. pp. 4428-4432. ISSN 1477-9226
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Official URL: http://dx.doi.org/10.1039/c8dt00110c
Abstract
Through-conjugation of two phosphaalkyne moieties within an
isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)2}2{μ-(CC)2C6H4-p}(CP)2], via base induced desilylation of [{Ru(dppe)2}2{μ-(CC)2C6H4 p}Cl2]. The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0146 Inorganic chemistry |
Related URLs: | |
Depositing User: | Ian Crossley |
Date Deposited: | 08 Mar 2018 13:55 |
Last Modified: | 01 Jul 2019 19:46 |
URI: | http://sro.sussex.ac.uk/id/eprint/74320 |
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📧 Request an updateFunder and Project Information
Project Name | Sussex Project Number | Funder | Funder Ref |
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Polymetallaphosphacarbons: Toward phosphorus-doped organometallic molecular wires | G1182 | ROYAL SOCIETY | UF120021 |
Linearly Conjugated Phosphacarbon Organometallics | G1810 | EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL | EP/N016785/1 |