Leech, Matthew C and Crossley, Ian R (2018) Through-conjugation of two phosphaalkyne (‘CP’) moieties mediated by a bimetallic scaffold†. Dalton Transactions, 47. pp. 4428-4432. ISSN 1477-9226

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Abstract

Through-conjugation of two phosphaalkyne moieties within an
isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)2}2{μ-(CC)2C6H4-p}(CP)2], via base induced desilylation of [{Ru(dppe)2}2{μ-(CC)2C6H4 p}Cl2]. The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Subjects:	Q Science > QD Chemistry > QD0146 Inorganic chemistry
Related URLs:	Publisher
Depositing User:	Ian Crossley
Date Deposited:	08 Mar 2018 13:55
Last Modified:	01 Mar 2019 02:00
URI:	http://sro.sussex.ac.uk/id/eprint/74320

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