Polynuclear ampyrone based 3d coordination clusters

Sampani, Stavroula I, Loukopoulos, Edward, Azam, Mohammad, Griffiths, Kieran, Abdul-Sada, Alaa, Tizzard, Graham J, Coles, Simon, Escuer, Albert, Tsipis, Athanasios and Kostakis, George E (2018) Polynuclear ampyrone based 3d coordination clusters. CrystEngComm (10). pp. 1315-1464. ISSN 1466-8033

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The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear Coordination Clusters with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Georgios Kostakis
Date Deposited: 29 Jan 2018 10:06
Last Modified: 02 Jul 2019 13:15
URI: http://sro.sussex.ac.uk/id/eprint/73185

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