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Polynuclear ampyrone based 3d coordination clusters

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posted on 2023-06-09, 11:48 authored by Stavroula Sampani, Edouardos Loukopoulos, Mohammad Azam, Kieran Griffiths, Alaa Abdul-Sada, Graham J Tizzard, Simon Coles, Albert Escuer, Athanasios Tsipis, George KostakisGeorge Kostakis
The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear Coordination Clusters with different structural motifs. An organic transformation occurs in the ligand in the Cu compound for which theoretical studies are presented. Solution studies, topological issues and magnetic studies are discussed. The present results demonstrate the richness of the coordination chemistry of this monoprotic organic ligand, which promotes the formation of high-nuclearity CCs

History

Publication status

  • Published

File Version

  • Accepted version

Journal

CrystEngComm

ISSN

1466-8033

Publisher

Royal Society of Chemistry

Issue

10

Page range

1315-1464

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2018-01-29

First Open Access (FOA) Date

2019-01-29

First Compliant Deposit (FCD) Date

2018-01-29

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