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Kühne, Irina A, Kostakis, George, Anson, Christopher E and Powell, Annie K (2016) An undecanuclear ferrimagnetic Cu9Dy2 SMM achieved through ligand fine-tuning. Inorganic Chemistry, 55 (9). pp. 4072-4074. ISSN 0020-1669
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Official URL: http://dx.doi.org/10.1021/acs.inorgchem.6b00490
Abstract
We describe the concept of increasing the nuclearity of a previously reported high-spin Cu5Gd2 core using a “fine tuning” ligand approach. Thus two Cu9Ln2 coordination clusters, with Ln = Dy (1), Gd(2) were synthesized with the Gd compound having a ground spin state of 17/2 and the Dy analogue showing SMM behavior in zero field.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0146 Inorganic chemistry |
Depositing User: | Georgios Kostakis |
Date Deposited: | 23 Nov 2017 14:21 |
Last Modified: | 02 Jul 2019 17:04 |
URI: | http://sro.sussex.ac.uk/id/eprint/71521 |
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