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An undecanuclear ferrimagnetic Cu9Dy2 SMM achieved through ligand fine-tuning

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posted on 2023-06-09, 09:00 authored by Irina A Kühne, George KostakisGeorge Kostakis, Christopher E Anson, Annie K Powell
We describe the concept of increasing the nuclearity of a previously reported high-spin Cu5Gd2 core using a “fine tuning” ligand approach. Thus two Cu9Ln2 coordination clusters, with Ln = Dy (1), Gd(2) were synthesized with the Gd compound having a ground spin state of 17/2 and the Dy analogue showing SMM behavior in zero field.

History

Publication status

  • Published

File Version

  • Accepted version

Journal

Inorganic Chemistry

ISSN

0020-1669

Publisher

American Chemical Society

Issue

9

Volume

55

Page range

4072-4074

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2017-11-23

First Open Access (FOA) Date

2017-11-23

First Compliant Deposit (FCD) Date

2017-11-23

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