Tsoureas, Nikolaos, Green, Jennifer C and Cloke, F Geoffrey N (2017) C-H and H-H activation at a Di-titanium centre. Chemical Communications, 53. pp. 13117-13120. ISSN 1359-7345

PDF - Accepted Version Available under License All Rights Reserved. Download (933kB)

Abstract

The reaction of the bis(pentalene)dititanium complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4(1,4-SiiPr3)2) with the N-heterocyclic carbene 1,3,4,5 tetramethylimidazol 2 ylidene results in intramolecular C-H activation of one of the iPr methyl groups of a Pn† ligand and formation of a "tucked-in" bridging hydride complex. The "tuck-in" process is reversed by the addition of hydrogen, which yields a dihydride featuring terminal and bridging hydrides.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Depositing User:	Helen Webb - Library
Date Deposited:	27 Oct 2017 09:56
Last Modified:	02 Jul 2019 14:15
URI:	http://sro.sussex.ac.uk/id/eprint/70705

View download statistics for this item

📧 Request an update