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Kilpatrick, Alexander F R and Cloke, F. Geoffrey N (2017) A base-free synthetic route to anti-bimetallic lanthanide pentalene complexes. Dalton Transactions, 46 (17). pp. 5587-5597. ISSN 1477-9226
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Official URL: http://dx.doi.org/10.1039/C6DT04475A
Abstract
We report the synthesis and structural characterisation of three homobimetallic complexes featuring divalent lanthanide metals (Ln = Yb, Eu and Sm) bridged by the silylated pentalene ligand [1,4-{SiiPr3}2C8H4]2− (= Pn†). Magnetic measurements and cyclic voltammetry have been used to investigate the extent of intermetallic communication in these systems, in the context of molecular models for organolanthanide based conducting materials.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Geoff Cloke |
Date Deposited: | 04 Jan 2017 10:59 |
Last Modified: | 02 Jul 2019 17:03 |
URI: | http://sro.sussex.ac.uk/id/eprint/66020 |
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