Ansell_et_al-2016-Advanced_Synthesis_&_Catalysis.pdf (752.12 kB)
Synthesis of functionalized hydrazines: facile homogeneous (n-heterocyclic carbene)-palladium(0)-catalyzed diboration and silaboration of azobenzenes
journal contribution
posted on 2023-06-09, 03:59 authored by Melvyn B Ansell, George KostakisGeorge Kostakis, Holger Braunschweig, Oscar Navarro Fernandez, John SpencerJohn SpencerThe bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)2(PhC=CPh)] (ITMe=1,3,4,5 tetramethylimidazol-2-ylidene) acts as a highly active pre catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.
Funding
DTA - University of Sussex 2013 (EPSRC); G1142; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/L505109/1
History
Publication status
- Published
File Version
- Published version
Journal
Advanced Synthesis and CatalysisISSN
1615-4150Publisher
Wiley-VCH VerlagExternal DOI
Issue
23Volume
358Page range
3765-3769Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-11-14First Open Access (FOA) Date
2016-11-14First Compliant Deposit (FCD) Date
2016-11-12Usage metrics
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