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Tetranuclear Zn2Ln2 coordination clusters as catalysts in Petasis borono-Mannich multicomponent reaction

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journal contribution
posted on 2023-06-09, 02:31 authored by Prashant Kumar, Kieran Griffiths, Smaragda Lymperopoulou, George KostakisGeorge Kostakis
We report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84-98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.

Funding

Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties; G1632; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/M023834/1

History

Publication status

  • Published

File Version

  • Accepted version

Journal

RSC Advances

ISSN

2046-2069

Publisher

Royal Society of Chemistry

Issue

82

Volume

6

Page range

79180-79184

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2016-08-11

First Open Access (FOA) Date

2017-08-15

First Compliant Deposit (FCD) Date

2016-08-11

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