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Kumar, Prashant, Griffiths, Kieran, Lymperopoulou, Smaragda and Kostakis, George E (2016) Tetranuclear Zn2Ln2 coordination clusters as catalysts in Petasis borono-Mannich multicomponent reaction. RSC Advances, 6 (82). pp. 79180-79184. ISSN 2046-2069
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Official URL: http://dx.doi.org/10.1039/C6RA17209A
Abstract
We report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84-98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0146 Inorganic chemistry |
Depositing User: | Georgios Kostakis |
Date Deposited: | 11 Aug 2016 10:02 |
Last Modified: | 02 Jul 2019 18:47 |
URI: | http://sro.sussex.ac.uk/id/eprint/62364 |
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📧 Request an updateFunder and Project Information
Project Name | Sussex Project Number | Funder | Funder Ref |
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Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties | G1632 | EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL | EP/M023834/1 |