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Tetranuclear Zn2Ln2 coordination clusters as catalysts in Petasis borono-Mannich multicomponent reaction
journal contribution
posted on 2023-06-09, 02:31 authored by Prashant Kumar, Kieran Griffiths, Smaragda Lymperopoulou, George KostakisGeorge KostakisWe report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84-98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.
Funding
Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties; G1632; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/M023834/1
History
Publication status
- Published
File Version
- Accepted version
Journal
RSC AdvancesISSN
2046-2069Publisher
Royal Society of ChemistryExternal DOI
Issue
82Volume
6Page range
79180-79184Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-08-11First Open Access (FOA) Date
2017-08-15First Compliant Deposit (FCD) Date
2016-08-11Usage metrics
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