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Braunschweig, Holger, Krummenacher, Ivo, Mailänder, Lisa, Pentecost, Leanne and Vargas, Alfredo (2016) Formation of a stable radical by oxidation of a tetraorganoborate. Chemical Communications, 43. pp. 7005-7008. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/C6CC02916G
Abstract
Herein, we describe the selective formation of a stable neutral spiroborate radical by one-electron oxidation of the corresponding tetraorganoborate salt Li[B(C4Ph4)2], formally containing a tetrahedral borate center and a s-cis-butadiene radical cation as the spin-bearing site. Spectroscopic and computational methods have been used to determine the spin distribution and the chromism observed in the solid state.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry |
Depositing User: | Alfredo Vargas |
Date Deposited: | 09 May 2016 14:58 |
Last Modified: | 02 Jul 2019 18:30 |
URI: | http://sro.sussex.ac.uk/id/eprint/60772 |
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