New outcomes of Lewis base addition to diboranes(4) electronic effects override strong steric disincentives CC.pdf (1.83 MB)
New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives
journal contribution
posted on 2023-06-09, 00:26 authored by Nicole Arnold, Holger Braunschweig, Alexander Damme, Rian D Dewhurst, Leanne Pentecost, Krzysztof Radacki, Sascha Stellwag-Konertz, Torsten Thiess, Alexandra Trumpp, Alfredo VargasAlfredo VargasTwo surprising new outcomes of the reaction of Lewis bases with dihalodiboranes(4) are presented, including sp2–sp3 diboranes in which the Lewis base unit is bound to a highly sterically congested boron atom, and a rearranged double base adduct. The results provide a fuller understanding of the reactivity of diboranes, a poorly-understood class of molecule of critical importance to synthetic organic chemistry.
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Publication status
- Published
File Version
- Published version
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
27Volume
52Page range
4898-4901Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-03-16First Open Access (FOA) Date
2017-02-02First Compliant Deposit (FCD) Date
2017-02-02Usage metrics
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