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Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects

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posted on 2023-06-09, 00:08 authored by Kieran Griffiths, Vassiliki N Dokorou, John SpencerJohn Spencer, Alaa Abdul-Sada, Alfredo VargasAlfredo Vargas, George KostakisGeorge Kostakis
This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2(LX)4(NO3)2(solv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)3 salts. Our synthetic work is further supported by DFT studies.

Funding

Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties; G1632; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/M023834/1

History

Publication status

  • Published

File Version

  • Published version

Journal

CrystEngComm

ISSN

1466-8033

Publisher

Royal Society of Chemistry

Issue

5

Volume

18

Page range

704-713

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2016-01-27

First Open Access (FOA) Date

2016-01-28

First Compliant Deposit (FCD) Date

2016-01-28

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