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Ansell, Melvyn B, Roberts, Debbie E, Cloke, F Geoffrey N, Navarro, Oscar and Spencer, John (2015) Synthesis of an (NHC)2Pd(SiMe3)2 (NHC = N-Heterocyclic Carbene) Complex. Catalytic, cis-Bis-Silylations of Internal Alkynes with Unactivated Disilanes. Angewandte Chemie International Edition, 54 (19). pp. 5578-5582. ISSN 1433-7851
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Official URL: http://dx.doi.org/10.1002/anie.201501764
Abstract
The novel complex cis-[(ITMe)2Pd(SiMe3)2 (ITMe =1,3,4,5-tetramethylimidazol-2-ylidene) has been synthesised by mild oxidative cleavage of Me3SiSiMe3 using (ITMe)2Pd(0). The use of this complex as precatalyst for the cis-bis-silylation of internal alkynes using unactivated disilanes is reported.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0146 Inorganic chemistry |
Depositing User: | John Spencer |
Date Deposited: | 27 Apr 2015 13:24 |
Last Modified: | 02 Mar 2021 11:21 |
URI: | http://sro.sussex.ac.uk/id/eprint/53800 |
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📧 Request an updateFunder and Project Information
Project Name | Sussex Project Number | Funder | Funder Ref |
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DTA - University of Sussex 2013 (EPSRC) | G1142 | EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL | EP/L505109/1 |