Ansell_et_al-2015-Angewandte_Chemie_International_Edition.pdf (4.21 MB)
Synthesis of an (NHC)2Pd(SiMe3)2 (NHC = N-Heterocyclic Carbene) Complex. Catalytic, cis-Bis-Silylations of Internal Alkynes with Unactivated Disilanes
journal contribution
posted on 2023-06-08, 20:38 authored by Melvyn B Ansell, Debbie E Roberts, Geoff Cloke, Oscar Navarro, John SpencerJohn SpencerThe novel complex cis-[(ITMe)2Pd(SiMe3)2 (ITMe =1,3,4,5-tetramethylimidazol-2-ylidene) has been synthesised by mild oxidative cleavage of Me3SiSiMe3 using (ITMe)2Pd(0). The use of this complex as precatalyst for the cis-bis-silylation of internal alkynes using unactivated disilanes is reported.
Funding
DTA - University of Sussex 2013 (EPSRC); G1142; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/L505109/1
History
Publication status
- Published
File Version
- Published version
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
WileyExternal DOI
Issue
19Volume
54Page range
5578-5582Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2015-04-27First Open Access (FOA) Date
2015-05-19First Compliant Deposit (FCD) Date
2015-04-27Usage metrics
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