University of Sussex
Browse

File(s) not publicly available

Complete and partial 1,2-additions across transition metal-boron double bonds

journal contribution
posted on 2023-06-08, 17:39 authored by Holger Braunschweig, Qing Ye, Alfredo VargasAlfredo Vargas, Rian D Dewhurst, Florian Hupp
The first 1,2-additions across a metal-boron double bond are reported, one a definitive chlorogallation of a Fe=B bond, the other a partial chlorogallation of a Mo=B bond that leads to a highly unusual, planar Mo-B-Ga-Cl rhombus. The two reactions occur with opposite regiochemistry, with the Ga atom bound to the Fe atom in the former and to both the Mo and B atoms in the latter. The bonding in the Mo adduct, as well as the reasons for the differing regiochemistry of the reaction, are explored computationally.

History

Publication status

  • Published

Journal

Journal of the American Chemical Society

ISSN

1520-5126

Publisher

American Chemical Society

Issue

27

Volume

136

Page range

9560-9563

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2014-06-25

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC