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Strained ansa half-sandwich complexes of ruthenium and osmium and a non-iron metallopolymer by ring-opening polymerization
journal contribution
posted on 2023-06-08, 16:54 authored by Holger Braunschweig, Theresa Dellermann, Rian D Dewhurst, Jan Mies, Krzysztof Radacki, Sascha Stellwag-Konertz, Alfredo VargasAlfredo VargasHerein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridged osmium species is reported, the first example of an ansa half-sandwich complex of this element.
History
Publication status
- Published
Journal
OrganometallicsISSN
1520-6041Publisher
American Chemical SocietyExternal DOI
Issue
7Volume
33Page range
1536-1539Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2014-04-01Usage metrics
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