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Strained ansa half-sandwich complexes of ruthenium and osmium and a non-iron metallopolymer by ring-opening polymerization

journal contribution
posted on 2023-06-08, 16:54 authored by Holger Braunschweig, Theresa Dellermann, Rian D Dewhurst, Jan Mies, Krzysztof Radacki, Sascha Stellwag-Konertz, Alfredo VargasAlfredo Vargas
Herein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridged osmium species is reported, the first example of an ansa half-sandwich complex of this element.

History

Publication status

  • Published

Journal

Organometallics

ISSN

1520-6041

Publisher

American Chemical Society

Issue

7

Volume

33

Page range

1536-1539

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2014-04-01

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