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Lanthanum does form stable molecular compounds in the +2 oxidation state
journal contribution
posted on 2023-06-08, 16:02 authored by Peter B Hitchcock, Michael F Lappert, Laurent Maren, Andrey V ProtchenkoGetting down to business: Reduction of the LaIII tricyclopentadienide complex [LaCp''3] (Cp''=?5-1,3-(SiMe3)2C5H3) by K and [18]crown-6 or [2,2,2]cryptand produced thermally stable mononuclear crystalline lanthanate(II) salts. The La +2 oxidation state in these complexes was confirmed both in solution (EPR) and the solid state (EPR, SQUID, X-ray diffraction) and was supported by a computational study.
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Publication status
- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
Wiley-VCH Verlag BerlinExternal DOI
Issue
8Volume
47Page range
1488-1491Department affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
Legacy Posted Date
2013-10-11Usage metrics
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