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Lanthanum does form stable molecular compounds in the +2 oxidation state

journal contribution
posted on 2023-06-08, 16:02 authored by Peter B Hitchcock, Michael F Lappert, Laurent Maren, Andrey V Protchenko
Getting down to business: Reduction of the LaIII tricyclopentadienide complex [LaCp''3] (Cp''=?5-1,3-(SiMe3)2C5H3) by K and [18]crown-6 or [2,2,2]cryptand produced thermally stable mononuclear crystalline lanthanate(II) salts. The La +2 oxidation state in these complexes was confirmed both in solution (EPR) and the solid state (EPR, SQUID, X-ray diffraction) and was supported by a computational study.

History

Publication status

  • Published

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Publisher

Wiley-VCH Verlag Berlin

Issue

8

Volume

47

Page range

1488-1491

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2013-10-11

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