Kilpatrick, Alexander F R, Green, Jennifer C, Cloke, F Geoffrey N and Tsoureas, Nikolaos (2013) Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond. Chemical Communications, 49. pp. 9434-9436. ISSN 1359-7345

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Abstract

The novel bimetallic bis(pentalene) complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4{SiiPr3-1,4}2) has been synthesised and structurally characterised. Structural data show a Ti–Ti distance of 2.399(2) Å, consistent with a strong metal–metal interaction, which DFT calculations best describe as a double bond with σ and π components

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Subjects:	Q Science
Depositing User:	Deeptima Massey
Date Deposited:	27 Sep 2013 13:01
Last Modified:	27 Sep 2013 13:01
URI:	http://sro.sussex.ac.uk/id/eprint/46462

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