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Confirming the existence of p-allyl-palladium intermediates during the reaction of meta photocycloadducts with palladium(ii) compounds
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posted on 2023-06-08, 14:28 authored by Clive S Penkett, Paul J Brann, Jason A Woolford, Rachel J KahanThe transient existence of p-allyl-palladium intermediates formed by the reaction of Pd(OAc)2 and anisole-derived meta photocycloadducts has been demonstrated using NMR techniques. The intermediates tended to be short-lived and underwent rapid reductive elimination of palladium metal to form allylic acetates, however this degradation process could be delayed by changing the reaction solvent from acetonitrile to chloroform.
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- Published
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- Published version
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
11Volume
49Page range
1106-1108Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2013-02-27First Open Access (FOA) Date
2013-12-14First Compliant Deposit (FCD) Date
2013-02-27Usage metrics
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