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Crossley, Ian R and Hayes, Jack (2012) Bis(methimazolyl)borate chemistry of palladium and platinum. Journal of Orgnometallic Chemistry, 716. pp. 285-288. ISSN 0022-328X
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Official URL: http://dx.doi.org/10.1016/j.jorganchem.2012.06.015
Abstract
The complexes [Pd{κ2-S,S′-H2B(mimMe)2}(η3-C3H4R)] (R = H, Me) have been obtained in high yield from the dichloromethane mediated reaction of the respective [Pd(Cl)(η3-C3H4R)] with K[H2B(mimMe)2]. Attempts to prepare analogous compounds of platinum have led instead to the observation of species consistent with incidences of B–H activation, including the unexpected and facile formation of [PtH(PPh3){κ4-B(mimMe)3}]Cl.
Item Type: | Article |
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Additional Information: | Online First Article |
Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0146 Inorganic chemistry |
Depositing User: | Ian Crossley |
Date Deposited: | 13 Aug 2012 08:35 |
Last Modified: | 13 Aug 2012 08:35 |
URI: | http://sro.sussex.ac.uk/id/eprint/40360 |