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Bis(methimazolyl)borate chemistry of palladium and platinum
The complexes [Pd{?2-S,S'-H2B(mimMe)2}(?3-C3H4R)] (R = H, Me) have been obtained in high yield from the dichloromethane mediated reaction of the respective [Pd(Cl)(?3-C3H4R)] with K[H2B(mimMe)2]. Attempts to prepare analogous compounds of platinum have led instead to the observation of species consistent with incidences of B–H activation, including the unexpected and facile formation of [PtH(PPh3){?4-B(mimMe)3}]Cl.
History
Publication status
- Published
Journal
Journal of Orgnometallic ChemistryISSN
0022-328XPublisher
ElsevierExternal DOI
Volume
716Page range
285-288Department affiliated with
- Chemistry Publications
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Online First ArticleFull text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-08-13Usage metrics
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