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Bis(methimazolyl)borate chemistry of palladium and platinum

journal contribution
posted on 2023-06-08, 12:13 authored by Ian CrossleyIan Crossley, Jack Hayes
The complexes [Pd{?2-S,S'-H2B(mimMe)2}(?3-C3H4R)] (R = H, Me) have been obtained in high yield from the dichloromethane mediated reaction of the respective [Pd(Cl)(?3-C3H4R)] with K[H2B(mimMe)2]. Attempts to prepare analogous compounds of platinum have led instead to the observation of species consistent with incidences of B–H activation, including the unexpected and facile formation of [PtH(PPh3){?4-B(mimMe)3}]Cl.

History

Publication status

  • Published

Journal

Journal of Orgnometallic Chemistry

ISSN

0022-328X

Publisher

Elsevier

Volume

716

Page range

285-288

Department affiliated with

  • Chemistry Publications

Notes

Online First Article

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-08-13

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