File(s) not publicly available
Stabilization of low-oxidation-state early transition-metal complexes bearing 1,2,4-triphosphacyclopentadienyl ligands: Structure of [{Sc(P(3)C(2)tBu(2))(2)}(2)];Sc-II or mixed oxidation state?
journal contribution
posted on 2023-06-08, 10:07 authored by Guy K B Clentsmith, Geoff Cloke, Jennifer C Green, John Hanks, Peter B Hitchcock, John F NixonScII or mixed oxidation state ScIII/ScI? Reduction of the homoleptic ScIII complex [Sc(P3C2tBu2)3] allows access to the subvalent [{Sc(P3C2tBu2])2}2] complex (see picture), in which the metal centers are formally bivalent. DFT calculations support fomulation of the reduced species as a mixed oxidation state.
History
Publication status
- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851External DOI
Issue
9Volume
42Page range
1038-1041Department affiliated with
- Chemistry Publications
Notes
Joint main author (with JF Nixon); all experimental work done at Sussex; the first report of the isolation and detailed characterisation of a scandium complex in the oxidation state of (II)- this compound thus completes the series of divalent metallocene sandwich complexes for the 1st row transition elements elements.Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC