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Coles, Martyn and Hitchcock, Peter (2002) Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand. Chemical Communications, - (23). pp. 2794-2795. ISSN 1359-7345
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Official URL: http://dx.doi.org/10.1039/B209026K
Abstract
Structural investigation of Li-complexes of the phospha(III)-guanidinate anion [Ph2PC{(NPr)-Pr-i}(2)](-) revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{(NPr)-Pr-i}(2))AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported.
Item Type: | Article |
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Additional Information: | MPC conducted all synthetic work and is the corresponding author. The first study of different bonding modes of the phosphaguanidinate anion within lithium complexes. A new class of metal functionalized phosphine ligand incorporated into a hetero-trimetallic complex. |
Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Martyn Coles |
Date Deposited: | 06 Feb 2012 21:26 |
Last Modified: | 30 Mar 2012 11:16 |
URI: | http://sro.sussex.ac.uk/id/eprint/31223 |