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Novel routes to the kainates: Stereoselectivity in addition reactions to pyrrole [1,2c]-oxazol-3-one

journal contribution
posted on 2023-06-08, 09:45 authored by A J Murray, P J Parsons, E S Greenwood, Eddy Viseux
This paper describes the addition of a range of electrophiles to 1. An unusual and unpredicted stereochemistry of addition has been observed in line with our original photochemical observations

History

Publication status

  • Published

Journal

SYNLETT

ISSN

0936-5214

Publisher

Thieme ejournals

Issue

9

Volume

2004

Page range

1589-1591

Pages

3.0

Department affiliated with

  • Chemistry Publications

Notes

EMEV did much of synthetic work, the computer based calculations and is principle author. This paper features a relevant discussion for the observation of the unexpected diastereocontrol during electrophilic additions on bicyclic 2,5-dihydro-1H-pyrroles, and presents theoretical calculations in an attempt to rationalise this outcome.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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