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Novel routes to the kainates: Stereoselectivity in addition reactions to pyrrole [1,2c]-oxazol-3-one
journal contribution
posted on 2023-06-08, 09:45 authored by A J Murray, P J Parsons, E S Greenwood, Eddy ViseuxThis paper describes the addition of a range of electrophiles to 1. An unusual and unpredicted stereochemistry of addition has been observed in line with our original photochemical observations
History
Publication status
- Published
Journal
SYNLETTISSN
0936-5214Publisher
Thieme ejournalsExternal DOI
Issue
9Volume
2004Page range
1589-1591Pages
3.0Department affiliated with
- Chemistry Publications
Notes
EMEV did much of synthetic work, the computer based calculations and is principle author. This paper features a relevant discussion for the observation of the unexpected diastereocontrol during electrophilic additions on bicyclic 2,5-dihydro-1H-pyrroles, and presents theoretical calculations in an attempt to rationalise this outcome.Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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