A Synthesis of an Ionomycin Calcium Complex

Gao, Zhangua, Li, Yingfa, Cooksey, John P, Snaddon, Thomas N, Schunk, Stefan, Viseux, Eddy M E, McAteer, Stephen M and Kocienski, Philip J (2009) A Synthesis of an Ionomycin Calcium Complex. Angewandte Chemie International Edition, 48 (27). pp. 5022-5025. ISSN 1433-7851

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A Synthesis of an Ionomycin Calcium Complex Caught in the middle : The ionomycin calcium complex (see structure ; O red, Ca green) was the target of an approach featuring the efficient asymmetric syn- thesis of an allene by a copper(I)-mediated anti-selective SN2 reaction, a highly stereoselective gold(III)-catalyzed cycloisomerization of an a-hydroxyallene, and a Rh-catalyzed rearrangement of an a-diazo-b-hydroxyketone.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Eddy Viseux
Date Deposited: 06 Feb 2012 21:13
Last Modified: 16 Oct 2012 09:38
URI: http://sro.sussex.ac.uk/id/eprint/30285
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