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Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes

journal contribution
posted on 2023-06-08, 09:17 authored by Michael D Fryzuk, Jason B Love, Steven J Rettig, Victor G Jr Young
The reaction of dihydrogen with a side-on bound dinitrogen complex of zirconium was investigated. Instead of a displacement of the dinitrogen moiety, which is the common mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended to primary silanes to produce a species that contained a nitrogen-silicon bond. In addition, an intermediate in the dihydrogen addition has been structurally characterized as having a bridging dihydrogen unit

History

Publication status

  • Published

Journal

Science

ISSN

0036-8075

Volume

275

Page range

1445 - 1447

ISBN

0036-8075

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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